Gold(I) and platinum(II) azolates as ligands in cationic Rhodium(I) complexes
- Uson, R. 1
- Oro, L.A. 1
- Ciriano, M.A. 1
- Pinillos, M.T. 1
- Cabeza, J.A. 1
-
1
Universidad de Zaragoza
info
ISSN: 0022-328X
Datum der Publikation: 1981
Ausgabe: 221
Nummer: 2
Seiten: 249-255
Art: Artikel
Andere Publikationen in: Journal of Organometallic Chemistry
Zusammenfassung
Several cationic heterometallic rhodium complexes have been obtained by using the complexes ImAuPPh3 or (az)2Pt(dpe) (az imidazolate (Im) or pyrazolate (Pz) anions) as ligands. Attempts to prepare rhodium(I)-gold(I) derivatives containing pyrazolate-bridging ligands proved unsuccessful, rearrangements giving the complexes [Y2Rh(μ-Pz)]2 and [Ph3PAu(μ-Pz)AuPPh32]ClO4, [Au(PPh3)2]ClO4 or AuClPPh3 as end-products. © 1981.