Gold(I) and platinum(II) azolates as ligands in cationic Rhodium(I) complexes

  1. Uson, R. 1
  2. Oro, L.A. 1
  3. Ciriano, M.A. 1
  4. Pinillos, M.T. 1
  5. Cabeza, J.A. 1
  1. 1 Universidad de Zaragoza
    info

    Universidad de Zaragoza

    Zaragoza, España

    ROR https://ror.org/012a91z28

Revista:
Journal of Organometallic Chemistry

ISSN: 0022-328X

Any de publicació: 1981

Volum: 221

Número: 2

Pàgines: 249-255

Tipus: Article

SCOPUS: 2-s2.0-0001002245 GOOGLE SCHOLAR

Altres publicacions en: Journal of Organometallic Chemistry

Resum

Several cationic heterometallic rhodium complexes have been obtained by using the complexes ImAuPPh3 or (az)2Pt(dpe) (az imidazolate (Im) or pyrazolate (Pz) anions) as ligands. Attempts to prepare rhodium(I)-gold(I) derivatives containing pyrazolate-bridging ligands proved unsuccessful, rearrangements giving the complexes [Y2Rh(μ-Pz)]2 and [Ph3PAu(μ-Pz)AuPPh32]ClO4, [Au(PPh3)2]ClO4 or AuClPPh3 as end-products. © 1981.