Química Orgánica e Inorgánica
Departament
Rafael
Fernandez Galan
Publicacions en què col·labora amb Rafael Fernandez Galan (19)
2022
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Guanidinates as Alternative Ligands for Organometallic Complexes
Molecules (Basel, Switzerland), Vol. 27, Núm. 18
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ZnEt2as a Precatalyst for the Addition of Alcohols to Carbodiimides
Organometallics, Vol. 41, Núm. 21, pp. 2949-2957
2020
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Reactivity of N-Phosphinoguanidines of the Formula (HNR)(Ph2PNR)C(NAr) toward Main Group Metal Alkyls: Facile Ligand Rearrangement from N-Phosphinoguanidinates to Phosphinimine-Amidinates
Inorganic Chemistry, Vol. 59, Núm. 20, pp. 15262-15275
2019
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9-Borabicyclo[3.3.1]nonane: A metal-free catalyst for the hydroboration of carbodiimides
Chemical Communications, Vol. 55, Núm. 21, pp. 3073-3076
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Unusual ligand rearrangement: From: N -phosphinoguanidinato to phosphinimine-amidinato compounds
Chemical Communications, Vol. 55, Núm. 19, pp. 2809-2812
2018
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Carbodiimides as catalysts for the reduction of CO2 with boranes
Chemical Communications, Vol. 54, Núm. 37, pp. 4700-4703
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Selective Three-Component Coupling for CO2 Chemical Fixation to Boron Guanidinato Compounds
Inorganic Chemistry, Vol. 57, Núm. 14, pp. 8404-8413
2017
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Simple ZnEt
2
as a catalyst in carbodiimide hydroalkynylation: Structural and mechanistic studies
Dalton Transactions, Vol. 46, Núm. 38, pp. 12923-12934
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Insertion reactions of small unsaturated molecules in the N-B bonds of boron guanidinates
Dalton Transactions, Vol. 46, Núm. 31, pp. 10281-10299
2016
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Dialkylboron guanidinates: Syntheses, structures and carbodiimide de-insertion reactions
Dalton Transactions, Vol. 45, Núm. 39, pp. 15350-15363
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Half-Sandwich Guanidinate-Osmium(II) Complexes: Synthesis and Application in the Selective Dehydration of Aldoximes
European Journal of Inorganic Chemistry, Vol. 2016, Núm. 3, pp. 393-402
2015
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Reactivity of the Dimer [{RuCl(μ-Cl)(η<sup>3</sup>:η<sup>3</sup>-C<inf>10</inf>H<inf>16</inf>)}<inf>2</inf>] (C<inf>10</inf>H<inf>16</inf> = 2,7-Dimethylocta-2,6-diene-1,8-diyl) toward Guanidines: Access to Ruthenium(IV) and Ruthenium(II) Guanidinate Complexes
Organometallics, Vol. 34, Núm. 12, pp. 2796-2809
2014
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Mixed amido-/imido-/guanidinato niobium complexes: Synthesis and the effect of ligands on insertion reactions
Dalton Transactions, Vol. 43, Núm. 46, pp. 17434-17444
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Unexpected mild C-N bond cleavage in a niobium iminocarbamoyl complex mediated by catalytically obtained guanidine ligands
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY
2013
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Asymmetric niobium guanidinates as intermediates in the catalytic guanylation of amines
Dalton Transactions, Vol. 42, Núm. 23, pp. 8223-8230
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Synthesis, characterization and reactivity of new dinuclear guanidinate diimidoniobium complexes
European Journal of Inorganic Chemistry, pp. 2940-2946
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Unexpected mild C-N bond cleavage mediated by guanidine coordination to a niobium iminocarbamoyl complex
Chemical Communications, Vol. 49, Núm. 77, pp. 8701-8703
2012
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New alkylimido niobium complexes supported by guanidinate ligands: Synthesis, characterization, and migratory insertion reactions
Organometallics, Vol. 31, Núm. 5, pp. 1840-1848
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Ruthenium(II) Arene complexes with asymmetrical guanidinate ligands: Synthesis, characterization, and application in the base-free catalytic isomerization of allylic alcohols
Organometallics, Vol. 31, Núm. 23, pp. 8301-8311