Publications (202) MIGUEL ANGEL RUIZ ALVAREZ publications

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2025

  1. Synthesis and protonation reactions of nitrosyl complexes [M2Cp(μ-κ:η5-C5H4)(μ-PR2)(CO)(NO)2] to give κ:η-NO-bridged derivatives (M = Mo, W; R = Cy, tBu)

    Journal of Organometallic Chemistry, Vol. 1025

2024

  1. C≡N and N≡O Bond Cleavages of Acetonitrile and Nitrosyl Ligands at a Dimolybdenum Center to Render Ethylidyne and Acetamidinate Ligands

    Inorganic Chemistry, Vol. 63, Núm. 7, pp. 3207-3211

  2. N[sbnd]O bond cleavage and N2 activation reactions of the Nitrosyl-Bridged complex [Mo2Cp2(µ-PtBu2)(µ-NO)(NO)2]

    Journal of Organometallic Chemistry, Vol. 1022

  3. Nitrosyl derivatives of the halide-bridged complexes [M2Cp2(μ-X)(μ-PtBu2)(CO)2] (M = Mo, W; X = Cl, I).

    Journal of Organometallic Chemistry, Vol. 1012

2023

  1. Cycloaddition and C-S Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Alkynes and Phenyl Isothiocyanate

    Organometallics, Vol. 42, Núm. 15, pp. 2052-2064

  2. E-H Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Hydrogen and p-Block Element Hydrides

    Organometallics, Vol. 42, Núm. 19, pp. 2826-2838

  3. Isocyanide Cycloaddition and Coordination Processes at Trigonal Phosphinidene-Bridged MoRe and MoMn Complexes

    Inorganics, Vol. 11, Núm. 9

  4. Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Sulfur and Selenium: From Chalcogenophosphinidene- to Trithiophosphonate-Bridged Derivatives

    Inorganic Chemistry, Vol. 62, Núm. 14, pp. 5677-5689

  5. X-ray-determined structure of the technetium complex [Tc2(μ-CO)2(NC5H5)2(CO)6] revisited: [Tc2(μ-OMe)2(NC5H5)2(CO)6] as the correct formulation

    Acta crystallographica. Section C, Structural chemistry, Vol. 79, pp. 395-398

2022

  1. Chemistry of a Nitrosyl Ligand κ:η-Bridging a Ditungsten Center: Rearrangement and N-O Bond Cleavage Reactions

    Inorganic Chemistry, Vol. 61, Núm. 38, pp. 14929-14933

  2. Heterometallic phosphinidene-bridged complexes derived from the phosphanyl complexes syn-[MCp(PHR*)(CO)2] (M = Mo, W; R* = 2,4,6-C6H2tBu3).

    Journal of Organometallic Chemistry, Vol. 977

  3. P-C, P-N, and M-N Bond Formation Processes in Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Diazoalkanes and Organic Azides to Build Three-to Five-Membered Phosphametallacycles

    Inorganic Chemistry, Vol. 61, Núm. 46, pp. 18486-18495

  4. Reactions of the unsaturated methyl-bridged complexes [Mo2Cp2(μ-CH3)(μ-PtBu2)(CO)x] (x = 1, 2) towards transition metal carbonyls: convenient dehydrogenative route to heterometallic methylidyne-bridged clusters

    Journal of Organometallic Chemistry, Vol. 959

2021

  1. A glimpse into the chemical reactivity of the unsaturated hydride [MoWCp2(H)(μ-PCy2)(CO)2]

    Journal of Organometallic Chemistry, Vol. 936

  2. Electronic Structure and Donor Ability of an Unsaturated Triphosphorus-Bridged Dimolybdenum Complex

    Inorganic Chemistry, Vol. 60, Núm. 15, pp. 11548-11561

  3. P[sbnd]C coupling reactions of pyramidal phosphinidene-bridged dimolybdenum complexes with alkynes

    Inorganica Chimica Acta, Vol. 516

2020

  1. A Bridging Carbonyl of Unlikely Geometry: On the True Nature of the Technetium Complex [Tc2(μ-CO)2(CO)6(NC5H5)2]

    ChemRxiv

  2. Efficient Synthesis and Multisite Reactivity of a Phosphinidene-Bridged Mo-Re Complex. A Platform Combining Nucleophilic and Electrophilic Features

    Inorganic Chemistry, Vol. 59, Núm. 14, pp. 9481-9485

  3. P-N and N-Mo Bond Formation Processes in the Reactions of a Pyramidal Phosphinidene-Bridged Dimolybdenum Complex with Diazoalkanes and Organic Azides

    Inorganic Chemistry, Vol. 59, Núm. 11, pp. 7869-7883

2019

  1. Coordination and Dehydrogenation of Diphosphine-Borane Ph2PCH2PPh2·BH3 at a Heterometallic MoRe Center to Give an Agostic Boryl-Bridged Derivative

    Inorganic Chemistry, Vol. 58, Núm. 23, pp. 16134-16143