Reactivity of a Cationic Non-Hydridic Triruthenium Carbonyl Cluster Complex with Anionic Reagents. Synthesis of New Tri- and Hexanuclear Derivatives

  1. Cabeza, Javier A. 1
  2. del Río, Ignacio 1
  3. Riera, Víctor 1
  4. Grepioni, Fabrizia 2
  1. 1 Instituto de Química Organometálica “Enrique Moles”, Facultad de Química, Universidad de Oviedo-CSIC, E-33071 Oviedo, Spain
  2. 2 Dipartimento di Chimica “G. Ciamician”, Universitá degli Studi di Bologna, via Selmi 2, I-40126 Bologna, Italy
Revista:
Organometallics

ISSN: 0276-7333,  1520-6041

Año de publicación: 1997

Volumen: 16

Número: 4

Páginas: 812-815

Tipo: Artículo

DOI: 10.1021/OM960552J GOOGLE SCHOLAR lock_openAcceso abierto editor

Otras publicaciones en: Organometallics

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  • Spectroscopic data for2:  (a) IR (CH2Cl2), ν(CO):  2085 (w), 2061 (s), 2031 (vs), 2000 (sh), 1986 (s) cm-1. (b)1H NMR (CD2Cl2):  7.33 (t,J= 7.8 Hz, 1 H, ampy H4), 6.69 (d,J= 7.8 Hz, 1 H, ampy H5), 6.47 (d,J= 7.8 Hz, 1 H, ampy H3), 4.87 (s, br, 1 H, ampy NH), 2.63 (s, 3 H, ampy Me) ppm. (c)13C{1H} NMR (CD2Cl2):  201.2 (1 C, CO), 198.5 (2 C, CO), 198.4 (2 C, CO), 197.1 (2 C, CO), 175.6 (2 C, CO) 175.3 (ampy C), 157.2 (ampy C), 137.3 (ampy C), 117.5 (ampy C), 105.5 (ampy C), 27.0 (ampy C) ppm.
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