Publications (92) MIGUEL ANGEL RUIZ ALVAREZ publications

filter_list Inorganic Chemistry

2025

  1. Synthesis and protonation reactions of nitrosyl complexes [M2Cp(μ-κ:η5-C5H4)(μ-PR2)(CO)(NO)2] to give κ:η-NO-bridged derivatives (M = Mo, W; R = Cy, tBu)

    Journal of Organometallic Chemistry, Vol. 1025

2024

  1. Nitrosyl derivatives of the halide-bridged complexes [M2Cp2(μ-X)(μ-PtBu2)(CO)2] (M = Mo, W; X = Cl, I).

    Journal of Organometallic Chemistry, Vol. 1012

2023

  1. E-H Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Hydrogen and p-Block Element Hydrides

    Organometallics, Vol. 42, Núm. 19, pp. 2826-2838

  2. Reactions of Heterometallic Phosphinidene-Bridged MoMn and MoRe Complexes with Sulfur and Selenium: From Chalcogenophosphinidene- to Trithiophosphonate-Bridged Derivatives

    Inorganic Chemistry, Vol. 62, Núm. 14, pp. 5677-5689

  3. X-ray-determined structure of the technetium complex [Tc2(μ-CO)2(NC5H5)2(CO)6] revisited: [Tc2(μ-OMe)2(NC5H5)2(CO)6] as the correct formulation

    Acta crystallographica. Section C, Structural chemistry, Vol. 79, pp. 395-398

2022

  1. Heterometallic phosphinidene-bridged complexes derived from the phosphanyl complexes syn-[MCp(PHR*)(CO)2] (M = Mo, W; R* = 2,4,6-C6H2tBu3).

    Journal of Organometallic Chemistry, Vol. 977

  2. Reactions of the unsaturated methyl-bridged complexes [Mo2Cp2(μ-CH3)(μ-PtBu2)(CO)x] (x = 1, 2) towards transition metal carbonyls: convenient dehydrogenative route to heterometallic methylidyne-bridged clusters

    Journal of Organometallic Chemistry, Vol. 959

2021

  1. A glimpse into the chemical reactivity of the unsaturated hydride [MoWCp2(H)(μ-PCy2)(CO)2]

    Journal of Organometallic Chemistry, Vol. 936

  2. Electronic Structure and Donor Ability of an Unsaturated Triphosphorus-Bridged Dimolybdenum Complex

    Inorganic Chemistry, Vol. 60, Núm. 15, pp. 11548-11561

  3. P[sbnd]C coupling reactions of pyramidal phosphinidene-bridged dimolybdenum complexes with alkynes

    Inorganica Chimica Acta, Vol. 516

2019

  1. One-step synthesis and P-H bond cleavage reactions of the phosphanyl complex: Syn -[MoCp{PH(2,4,6-C6H2tBu3)}(CO)2] to give heterometallic phosphinidene-bridged derivatives

    Dalton Transactions, Vol. 48, Núm. 39, pp. 14585-14589

2018

  1. N-O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M 2 Cp 2 (μ-PCy 2 )(μ-NO)(NO) 2 ] (M = Mo, W)

    Inorganic Chemistry, Vol. 57, Núm. 24, pp. 15314-15329

  2. Phosphinidene-Bridged MoMn Derivatives of the Thiophosphinidene Complex [Mo2Cp2(μ-κ2:κ1,η6-SPMes∗)(CO)2] (Mes∗ = 2,4,6-C6H2tBu3)

    Inorganic Chemistry, Vol. 57, Núm. 4, pp. 1901-1911

2017

  1. Phosphinidene-bridged binuclear complexes

    Coordination Chemistry Reviews, Vol. 330, pp. 1-36

  2. Sn-H bond additions to asymmetric trigonal phosphinidene-bridged dimolybdenum complexes

    RSC Advances, Vol. 7, Núm. 53, pp. 33293-33304

  3. Terminal: Vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study

    Dalton Transactions, Vol. 46, Núm. 31, pp. 10440-10451

2016

  1. P-S bond cleavage in reactions of thiophosphinidene-bridged dimolybdenum complexes with [Co2(CO)8] to give phosphinidene-bridged heterometallic derivatives

    Dalton Transactions, Vol. 45, Núm. 5, pp. 1937-1952

2015

  1. Activity of Mo-Mo and Mo-P multiple bonds at the phosphinidene complex [Mo2Cp2{μ-P(2,4,6-C6H2tBu3)}(μ-CO)2] in reactions with isocyanides and phosphine ligands

    Inorganica Chimica Acta, Vol. 424, pp. 103-115

  2. Carbyne-carbyne coupling and h-shifts in reactions of the unsaturated methoxy- and hydroxycarbyne complexes [Mo2Cp2(μ-COR)(μ-CPh)(μ-PCy2)]+ with CO and Isocyanides

    Organometallics, Vol. 34, Núm. 9, pp. 1681-1691

  3. Diphosphorus-bridged heterometallic anions and hydrides derived from reactions of complex [Mo2Cp2(μ-PCy2)(μ-κ2:κ2-P2)(CO)2]- with precursors of 16-electron metal carbonyl fragments

    Journal of Organometallic Chemistry, Vol. 791, pp. 279-288