
MIGUEL ANGEL
RUIZ ALVAREZ
Catedrático de Universidad
Publications (30) MIGUEL ANGEL RUIZ ALVAREZ publications
2018
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N-O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M 2 Cp 2 (μ-PCy 2 )(μ-NO)(NO) 2 ] (M = Mo, W)
Inorganic Chemistry, Vol. 57, Núm. 24, pp. 15314-15329
2017
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Structure and dynamics of heterometallic clusters derived from addition of metal carbonyl fragments to the unsaturated hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2]
Dalton Transactions, Vol. 46, Núm. 44, pp. 15317-15329
2013
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Hydrogen atom transfer reactions of the unsaturated hydroxycarbyne complex [W2Cp2(μ-COH)(μ-PPh2)2]BF 4
Organometallics, Vol. 32, Núm. 16, pp. 4624-4635
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Novel dimerization of maleic anhydride at a Mo2 complex: Phase-driven keto/enol tautomerism in a phosphinidenium-ylide complex
Organometallics, Vol. 32, Núm. 21, pp. 6178-6181
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Stepwise hydrogenation of an arylthiophosphinidene isocyanide complex to give tethered aldimine and aminocarbene functions
Dalton Transactions, Vol. 42, Núm. 31, pp. 11039-11042
2012
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Protonation reactions of the oxo complex cis-[Mo 2(η 5-C 5H 5) 2(O)(μ-PPh 2) 2(CO)]. Hydroxo and tetrafluoroborate derivatives
Journal of Organometallic Chemistry, Vol. 699, pp. 67-74
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Reactions of the unsaturated hydroxo complex [W 2Cp 2(OH)(μ- PPh 2) 2(CO)]BF 4 with mono- and bidentate ligands having E-H bonds (E = O, S, N)
Inorganic Chemistry, Vol. 51, Núm. 19, pp. 10427-10436
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Reversible P-C coupling reactions at the unsaturated dimolybdenum carbyne complex [Mo 2(η 5-C 5H 5) 2(CPh)(μ-PCy 2)(μ-SPh)(CO)] +
Organometallics, Vol. 31, Núm. 20, pp. 7181-7190
2011
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C-X bond formation and cleavage in the reactions of the ditungsten hydride complex [W2(η5-C5H5) 2(H)(μ-PCy2)(CO)2] with small molecules having multiple C-X bonds (X = C, N, O)
Dalton Transactions, Vol. 40, Núm. 33, pp. 8294-8297
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Multisite reactivity of the central Mo2CP core in the unsaturated carbyne-bridged complex [Mo2(η5-C 5H5)2(μ-CPh)(μ-PCy2)(CO) 2]
Organometallics, Vol. 30, Núm. 14, pp. 3694-3697
2010
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Alkyne to carbyne coupling reactions of the unsaturated methoxycarbyne-bridged complex [Mo2(η5-C5H5)2(μ-COMe)(μ-PCy2)(CO)2]
Journal of Organometallic Chemistry, Vol. 695, Núm. 10-11, pp. 1592-1597
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Chemical and structural effects of bulkness on bent-phosphinidene bridges: Synthesis and reactivity of the diiron complex [Fe2Cp 2{μ-P(2,4,6-C6H2tBu 3)}(μ-CO)(CO)2]
Organometallics, Vol. 29, Núm. 8, pp. 1875-1878
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Synthesis and reactivity of the triply bonded binuclear anion [W 2(η5-C5H5)2μ- PCy2] (μ-CO)2-: Tungsten makes a difference
Organometallics, Vol. 29, Núm. 3, pp. 512-515
2008
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Aurophilic self-assembly of a Mo4Au2 phosphinidene complex with an unprecedented H-shaped planar metal core
Inorganic Chemistry, Vol. 47, Núm. 18, pp. 7963-7965
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From coordinated oxophosphinidene to O,O,P-bound arylhypophosphite(2-) to build a singular Mo2Sn2O2P2 metallocycle
Inorganic Chemistry, Vol. 47, Núm. 4, pp. 1252-1254
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Multisite reactivity of the unsaturated methoxycarbyne complex [Mo 2(η5-C5H5)2(μ- COMe)(μ-PCy2)(μ-CO)]
Organometallics, Vol. 27, Núm. 2, pp. 169-171
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Nucleophilic and electrophilic behavior of the phosphinidene-bridged complex[Fe2(η5-C5H5) 2(μ-PCy)(μ-CO)(CO)2]
Organometallics, Vol. 27, Núm. 6, pp. 1037-1040
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Reactivity of the α-agostic methyl bridge in the unsaturated complex [Mo2(η5-C5H5) 2(μ-η1:η2-CH3)(μ- PCy2)(CO)2]: Migratory behavior and methylidyne derivatives
Organometallics, Vol. 27, Núm. 9, pp. 1973-1975
2007
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Chemistry of unsaturated group 6 metal complexes with bridging hydroxy- and methoxycarbyne ligands. 2. Synthesis, structure, and bonding of 32- and 34-electron complexes
Organometallics, Vol. 26, Núm. 24, pp. 5912-5921
2006
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Dimolybdenum-tin derivatives of the unsaturated hydride [Mo 2(η5-C5H5)2(μ-H) (μ-PCy2)(CO)2] and HSnR3 (R = Ph, Bu): Bridging versus terminal coordination of the triorganostannyl group
Organometallics, Vol. 25, Núm. 22, pp. 5374-5380